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UID:news700@chemie.unibas.ch
DTSTAMP;TZID=Europe/Zurich:20251016T160603
DTSTART;TZID=Europe/Zurich:20251104T170000
SUMMARY:Light-driven Chemistry in the First Transition Series: Challenges a
 nd Opportunities (Camille & Henry Dreyfus Lecture 2025)
DESCRIPTION:There has been considerable renewed interest in the photophysic
 al properties of first-row transition metal complexes\, driven in part by 
 a long-standing desire to shift to earth-abundant materials for a variety
  of photolytic applications. A significant challenge to achieving this goa
 l is the fundamental difference in the excited-state properties of first-
 row metal complexes as compared to their second- and third-row congeners 
 subsequent to light absorption. Our group has been working on understandi
 ng the origins of this difference in an effort to develop design principl
 es that will assist in overcoming these intrinsic challenges and develop n
 ew paradigms for the creation of photo-active first-row chromophores for 
 applications in solar energy conversion strategies as well as photoredox 
 catalysis. This presentation will provide a brief survey of the work we h
 ave been engaged in over the past several years employing a combination of
  synthetic chemistry and ultrafast spectroscopy.\\r\\nCamille & Henry Drey
 fus LectureshipIn memory of the Dreyfus brothers\, the Camille and Henry D
 reyfus Foundation Inc. has established the Camille & Henry Dreyfus Lecture
 ship at the University of Basel [https://chemie.unibas.ch/de/aktuelles/ver
 anstaltungen/dreyfus-lectureship/]. The annual Lectureship brings a leadin
 g chemist from the United States to the Basel campus to deliver a series o
 f talks\, and to meet with faculty and students in order to enhance the re
 lationship between Swiss and U.S. science.
X-ALT-DESC:<p>There has been considerable renewed interest in the photophys
 ical properties of first-row transition metal complexes\, driven in part b
 y a long-standing desire to shift to earth-abundant&nbsp\;materials for a 
 variety of photolytic applications. A significant challenge to achieving t
 his goal&nbsp\;is the fundamental difference in the excited-state properti
 es of first-row metal complexes&nbsp\;as compared to their second- and thi
 rd-row congeners subsequent to light absorption. Our&nbsp\;group has been 
 working on understanding the origins of this difference in an effort to de
 velop&nbsp\;design principles that will assist in overcoming these intrins
 ic challenges and develop new&nbsp\;paradigms for the creation of photo-ac
 tive first-row chromophores for applications in solar&nbsp\;energy convers
 ion strategies as well as photoredox catalysis. This presentation will pro
 vide&nbsp\;a brief survey of the work we have been engaged in over the pas
 t several years employing a combination of synthetic chemistry and ultrafa
 st spectroscopy.</p>\n<p><strong>Camille &amp\; Henry Dreyfus Lectureship<
 /strong><br />In memory of the Dreyfus brothers\, the Camille and Henry Dr
 eyfus Foundation Inc. has established the <a href="https://chemie.unibas.c
 h/de/aktuelles/veranstaltungen/dreyfus-lectureship/" target="_blank">Camil
 le &amp\; Henry Dreyfus Lectureship at the University of Basel</a>. The an
 nual Lectureship brings a leading chemist from the United States to the Ba
 sel campus to deliver a series of talks\, and to meet with faculty and stu
 dents in order to enhance the relationship between Swiss and U.S. science.
 </p>
DTEND;TZID=Europe/Zurich:20251104T183000
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